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Ni(II)-selective PVC membrane sensor based on 1,2,4-triazole bis Schiff base ionophore: Synthesis, characterization and application for potentiometric titration of Ni2+ ions against EDTA
Faculty
Science
Year:
2021
Type of Publication:
ZU Hosted
Pages:
Authors:
Amr Lotfy Saber Hefny
Staff Zu Site
Abstract In Staff Site
Journal:
Arabian Journal of Chemistry ُُElsevier
Volume:
Keywords :
Ni(II)-selective , membrane sensor based , 1,2,4-triazole , Schiff
Abstract:
This study involves the preparation and investigation of a novel and highly selective poly (vinyl chloride)-based membrane of 2-((5-(2-hydroxy-3-methoxybenzylideneamino)-2H-1,2,4-tria zol-3-ylimino)methyl)-6-methoxyphenol Schiff base ligand (HMBT), which is a neutral ionophore with sodium tetraphenyl borate (STB) in the form of an excluder and o-nitrophenyloctyl ether (o-NPOE) in the form of solvent mediators (plasticizing) as a Ni(II)-selective electrode. The observation of optimal performance was done wherein the membrane was shown to have the HMBT–PVC–NPOE-STB composition of 4:32:63:1.It worked effectively across a broad range of concentration (1.0 108 to 1.0 102 mol L1 ). Meanwhile, the Nernstian slope was recorded as 29.3 mV per decade of activity between pH 3.0 and 8.0. The response time of this electrode was fast at 11 s which was used for a span of 100 days with sound reproducibility. According to the selectivity coefficients for trivalent, divalent, and monovalent cations, excellent selectivity was indicated for Ni(II) ions across a large number of citations, whereas no interference was caused by anions like PO4 3, SO4 2 and Cl. The proposed method in this study was applied successfully to determine Ni(II) content in different samples of water, obtaining suitable recoveries. Addition- ally, the probed sensor is utilized as indicator electrode when considering Ni 2+ ion potentiometric titration against EDTA. In addition, the chelate’s geometry and structure of the complex formed between Ni 2+ ions and HMBT, abbreviated as HMBT-Ni 2, was evaluated by separating the solid
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Amr Lotfy Saber Hefny, "Recognition and Quantification of Some Monoamines Neurotransmitters", Wiley, 2016
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Amr Lotfy Saber Hefny, "A Raman Spectroscopy Study of Chromium (III) Oxide in a Chromium–50 wt.% Nickel Alloy", UL BITWY WARSZAWSKIEJ 1920 R NR 3, WARSZAWA, POLAND, PL-02 362, 2016
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Amr Lotfy Saber Hefny, "Determination of Cr(III) ions in Different Water Samples Using Chromium(III)-sensor Based on N-[4-(dimethylamino) benzylidene]-6-nitro-1,3-benzothiazol-2-amine", Int. J. Electrochem. Sci., 9 (2014) 4932., 2014
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Amr Lotfy Saber Hefny, "Selective potentiometric method for determination of flucloxacillin antibiotic", Elsevier, 2013
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